Celebrities never fail to surprise us. Whether it’s risky movie roles, unexpected career moves or shocking confessions. But let’s be honest for a moment: what we’re always dying to know is who’s dating who and who’s just broke whose heart. While the mammoth of celebrity couples, Brangelina, shocked us with the announcement of separation, we’d like to take a moment and remember the couples we can’t believe matched in the first place.
20. Drew Barrymore and David Arquette
David Arquette certainly had fun on the set of the Scream trilogy. Not only did he marry his on-screen love interest Courteney Cox, but he recently revealed that he had a thing going on with Drew Barrymore, too. Although sources reveal Arquette and Barrymore dated long before they had to run away from the Ghostface together — they were an item in 1991.